MCM-48介孔分子筛的合成研究

本文以正硅酸乙酯(TEOS)为硅源,以十六烷基三甲基溴化胺(CTAB)为模板剂,用传统的水热合成法合成介孔分子筛MCM-48,探索模板剂、水、氢氧化钠等不同因素对合成MCM-48介孔分子筛的影响。在较低模板剂用量的条件下,合成了介孔分子筛,用XRD对MCM-48介孔分子筛进行了结构表征。     

Improved Non-Sieving Quadratic Sieve

In this paper, we give about prime numbers and Blum two theorems and one guess integers.We prove the two theorems about Blum integers.Combining the guess with the primitive non-sieving quadratic sieve,we proposed a improved non-sieving quadratic sieve（INQS）.In INQS,we not only reduce the times of squares and modulo n, but also imply another important conclusion,that is,we don＇t need to find the greatest common divisor of two integers as we do in PNQS.By some examples,we compare it with the primitive non-sieving quadratic sieve（PNQS）. It＇s faster to factor a integer by using improved non-sieving quadratic sieve than the primitive one.     

仲丁醇在Cu-ZnO-Cr2O3/SiO2催化剂上的脱 氢

采用浸渍法制备Cu-ZnO-Cr₂O₃/SiO₂ 催化剂, 考察了反应条件和催化剂的制备条件对 仲丁醇脱氢活性和选择性的影响. 借助XRD, TPD, TPR和BET等手段对催化剂进行表征， 结果表明， 催化剂的焙烧温度、 还原温度、 还原时间和载体的预处理对仲丁醇的转化率 和甲乙酮的选择性均有较大影响. 通过实验获得了最佳的反应和催化剂制备条件.     

分子马达定向运动的瞬态过程

本文研究了在一维三态周期跳跃模型下分子马达定向运动的瞬态过程，对于给定的任意初始分布，得出了与时间有关的几率分布的解析表达式，包括到达稳态之前的所有的瞬态过程，由此可获得马达在各个时刻的漂移速度和扩散系数，这是与对时间有关的两态模型的一上推广，同时还计算了马达到达稳态所需要的特征时间，并把结果同实验及其他计算结果进行了比较，与实验值符合的较好。     

Mechanism of selective separation on the surface of ionic sieve of removal of lead

This note describes a kind of ionic sieve with high selectivity to remove trace lead in water, in which stannic molybdopyrophosphate is used to be the substrate. The mechanism of selective separation on the surface of ionic sieve of removal of lead was explored by analyzing fourier transformation infrared spectra (FTIR), X-ray photoelectron spectrometry (XPS) and the results of selective adsorptivity experiment. The investigation suggests that in the process of synthesizing ionic sieve the olation reactions occur in solid phase by thermodynamic recrystallization and the adsorption units with special selectivity to lead are formed by chemical modification. After the ion exchange for Pb²⁺, the oaltion reactions not only keep the microstructures of adsorption units from collapse, but also provide lead cavties with special selectivity to lead ion that are capable of having special binding “memory effect” to Pb²⁺ by SnO₃ ²⁻ and P₂O₇ ⁴⁻ groups on the surface of this ionic sieve. Meanwhile, the selective separation capacity is a kind of weak chemical effect that is relative to the valence electron state of the adsorbed ion directly and tightly.     

汞的生物毒性及其防治策略

汞是一种剧毒环境污染物。汞与生物大分子上的活性点结合,使其失去活性,导致病变。     

非酸催化合成3,9-二苯基-2,4,8,10-四氧杂螺[5,5]-十一烷

利用苯甲醛与季戊四醇在非酸催化剂的作用下 ,合成了聚缩醛螺胞二醚的先导化合物3,9-二苯基 - 2 ,4,8,1 0 -四氧杂螺 [5 ,5 ]-十一烷 .考察了催化剂、反应物的摩尔比、带水剂、反应温度等对反应的影响 .利用FTIR、TG及HNMR对标题化合物的结构进行了表征 ,产品的最高收率可达 88%以上 .     

CdTe:Fe2+中远红外光谱的动态阳-泰勒效应

用一个基于线性阳泰勒效应的理论计算来处理Fe2 离子在CdTe中的远红外光谱;;并且考虑了来自配体Te的自旋轨道耦合对远红外光谱的贡献.计算结果不仅与远红外光谱的实验符合;;还与中子散射数据符合.最近研究中发现的CdTe:Fe2 中配体Te自旋轨道耦合的重要贡献在此得到证实.     

IRAS／Cirrus7中的尘埃辐射

根据IRAS四个波段的红外辐射流量,并认为尘埃粒子的红外吸收系数对波长的依赖关系为下列形式Q_(abs)∝λ~(-n),导出了IRAS/Cirrus 7中的观测尘埃温度T_d,辐射峰值波长λ_m及尘埃的远红外光学厚度τ_(60μ),τ_(100μ)。与由浸没在银河系总辐射场中的尘埃粒子模型所予言的平衡温度比较,讨论了IRAS/Cirrus 7中尘埃粒子的尺度,成分等性质以及对尘埃粒子加热的能量来源。     

孔结构对低碳醇催化剂性能的影响

考察了热处理和成型条件对铜基合成低碳混合醇催化剂孔结构,以及通过孔结构对活性、选择性的影响。实验结果表明,煅烧温度、煅烧时间和成型压力对催化剂孔结构都有明显的影响,通过控制孔结构参数来改变宏观催化性能的潜力是很大的。